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31.
Philippe E. Raison Regis Jardin Daniel Bouëxière Rudy J. M. Konings Thorsten Geisler Claudiu C. Pavel Jean Rebizant Karin Popa 《Physics and Chemistry of Minerals》2008,35(10):603-609
The crystallographic structures of the synthetic cheralite, CaTh(PO4)2, and its homolog CaNp(PO4)2 have been investigated by X-ray diffraction at room temperature. Rietveld analyses showed that both compounds crystallize in the monoclinic system and are isostructural to monazite LnPO4 (Ln = La to Gd). The space group is P21/n (I.T. = 14) with Z = 2. The refined lattice parameters of CaTh(PO4)2 are a = 6.7085(8) Å, b = 6.9160(6) Å, c = 6.4152(6) Å, and β = 103.71(1)° with best fit parameters R wp = 4.87%, R p = 3.69% and R B = 3.99%. For CaNp(PO4)2, we obtained a = 6.6509(5) Å, b = 6.8390(3) Å, c = 6.3537(8) Å, and β = 104.12(6)° and R wp = 6.74%, R p = 5.23%, and R B = 6.05%. The results indicate significant distortions of bond length and angles of the PO4 tetrahedra in CaTh(PO4)2 and to a lesser extent in CaNp(PO4)2. The structural distortions were confirmed by Raman spectroscopy of CaTh(PO4)2. A comparison with the isostructural compounds LnPO4 (Ln = Ce and Sm) confirmed that the substitution of the large rare earth trivalent cations with Ca2+ and Th4+ introduces a distortion of the PO4 tetrahedra. 相似文献
32.
This article describes a unique flood hazard, produced by the dramatic expansion of wetlands in Nelson County, located within
the North American Prairie Pothole Region of North Dakota, USA. There has been an unprecedented increase in the number, average
size, and permanence of prairie wetlands, and a significant increase in the size of a closed lake (Stump Lake) due to a decade-long
wet spell that began in 1993 following a prolonged drying trend. Base-line land cover information from the 1992 USGS National
Land Cover Characterization dataset, and a Landsat TM scene acquired 9 July 2001 are used to assess the growth of the closed
lake and wetland pond surface areas, and to analyze the type and area of various land cover classes inundated between 1992
and 2001. The open water profile in Nelson County changed from one marked by relatively comparable coverage of closed lake
and wetland pond areas in 1992, to one in which wetland open water accounted for the vast majority of total open water in
2001. The bulk of the wetland pond area expansion occurred by displacing existing wetland vegetation and agricultural cropland.
Producers responded to the flood hazard by filing Federal Crop Insurance Corporation (FCIC) claims and enrolling cropland
in the Conservation Reserve Program (CRP), a federal land retirement program. Land taken out of agricultural production has
had an enormous impact upon the agricultural sector that forms the economic base of the rural economy. In 2001 the land taken
out of production due to CRP enrollment and preventive planting claims represented nearly 42% of Nelson County’s 205.2 K ha
base agricultural land. The patterns obtained from this detailed study of Nelson County are likely to be the representative
of the more publicized flood disaster occurring within the Devils Lake Basin of North Dakota. 相似文献
33.
We test the hypothesis that flexural isostatic compensation of the mass removed by enhanced Quaternary erosion is responsible for uplift of the Western European Alps and their forelands. We use two well‐preserved and well‐dated (1.8 Ma) abandonment surfaces of foreland basin remnants in SE France (the Chambaran and Valensole plateaux) as passive benchmarks for tilting of the foreland. Estimating their initial slope from morphometric scaling relationships, we determine bulk post‐depositional tilting of 0.5–0.8% for these surfaces. The calculated isostatic response of the Alpine lithosphere to erosional unloading, using the method recently proposed by Champagnac et al. [Geology 35 (2007) 195–198] , yields a predicted tilting of 0.3–0.4% in the considered areas, explaining approximately half of the determined post‐depositional tilting. Such long‐term deformation being insensitive to cyclic loading/unloading because of glaciations, we suspect the other half to be related to as yet undetermined long‐wavelength and long‐lived tectonic process(es). 相似文献
34.
深水沉积层序特点及构成要素 总被引:6,自引:0,他引:6
本文在回顾当前国际上深水沉积研究热点的基础上,结合在墨西哥湾深水研究的成果系统描述了深水沉积的定义、形成机理、深水沉积层序及深水沉积构成要素的特点.深水沉积主要是在重力流作用下深水环境的沉积,主要形成于相对水平面下降和早期上升的时期,主要分布在低位体系域中.深水层序以凝缩段为边界,块状搬运沉积最早形成并直接位于层序界面上,其上被河道-天然堤沉积所覆盖.典型深水沉积的要素主要由河道、天然堤及越岸沉积、板状砂、块状搬运沉积等构成,这些沉积要素时空上有序地分布.深水河道是物源的主要通道和沉积的重要场所,从上游至下游河道弯曲度增加,能量逐渐减弱.侧向迁移明显,垂向上由富砂的顺直河道演化为相对富泥的弯曲河道.天然堤及越岸沉积以泥质为主,天然堤沿河道呈楔状分布,其近端砂岩含量高,地层厚且倾角较陡;远端砂岩含量低,地层薄且平缓,侧向连续性好但垂向连续性差.板状砂主要为深水扇前缘非限制性沉积,可分为块型和层型.块型侧向连续性好,同时垂向连通性高.层型侧向连续性好,垂向连通性差.块状搬运沉积主要是低水位期坡上沉积物失稳形成的各类滑塌体及碎屑流,其对下伏地层侵蚀明显,分布广泛,变形构造常见,可作为油气良好的封盖层. 相似文献
35.
With an appropriate system of higher order approximations the Faraday-effect is calculated for instantaneous ionospheric models the data of which are derived from the results of vertical soundings. Only one parameter which corresponds to the thickness of the outer ionosphere is left open; it is determined by global comparison with simultaneous Faraday-observations of satellite emissions. The thickness parameter shows various forms of variation with latitude; an increase towards north is the rule for quiet daytime conditions. Comparison with local methods shows considerable differences due to the indetermination of the absolute number of rotations. 相似文献
36.
Methods are described for the complexometric determination of calcium and magnesium in seawater, using an amalgamated silver electrode for end-point detection. In the presence of a small amount of mercury(II)-chelonate, the amalgamated silver electrode serves as a pM indicator during the complexometric titration, the Hg complex being stronger than Ca, Mg and Sr complexes. Calcium is determined by titration with EGTA, calcium+magnesium+strontium by titration with EDTA and magnesium is obtained by difference. Average values of 0.02120 (standard deviation 0.00004) for Ca:Cl‰ and 0.06671 (standard deviation 0.00014) for Mg:Cl‰ were obtained for samples from tropical North Atlantic Ocean. 相似文献
37.
The asteroid Patiria miniata was used to develop a static bioassay for various crude oil water-soluble fractions (WSF). The criterion used is the size of 48-h exposed embryos. The reasons for choosing this species and the growth criterion are discussed. Experiments show that the body length of 48-h exposed embryos is inversely proportional to hydrocarbon concentration of the WSF and the time of exposure. It is also shown that the toxicity of the WSF decreases with the age of the preparation and that the first 12 h following fertilisation are most sensitive to the effects of WSF. 相似文献
38.
Abstract. The consequences of the following episodic phenomena for the pelagic-benthic coupling in the Nordic Seas are illustrated: (1) Advection of water masses between fjords and shelf environments, (2) freshwater run-off and vertical stability, (3) dynamics of the marginal ice zone in the central and northern Barents Sea and the Polar Ocean, (4) drift patterns of sinking particles along the North Norwegian coast, (5) advection of zooplankton into subarctic fjords and the southern Barents Sea, zooplankton overwintering and composition, and (6) transport of organic particulate matter from the Barents Sea shelf. It is shown that physical processes in the north-eastern North Atlantic and Polar Ocean can be strongly variable on time scales of days to decades. They have a significant influence on the dynamics of pelagic-benthic coupling. The physical oceanography influences the vertical and horizontal particle flux not only directly (mixing, advection, up- and down-welling), but also indirectly through its impact on the biota (for example radiation, wind, ice cover, freshwater run-off and overwintering, advection and retention of zooplankton). Understanding pelagic-benthic coupling at high latitudes depends even more on a best possible understanding of the physical oceanography and the time scales involved than elsewhere. 相似文献
39.
40.
Jean Pierre Baudin 《Marine environmental research》1982,7(3):227-233
Uptake of 65Zn by Gammarus aequicauda results in a concentration factor of approximately 50 and it is characterised by a maximal accumulation level attained as early as the third day of the experiment. After ingestion by the gammarids of twenty contaminated meals which are distributed over a 45-day period, a transfer of 65Zn between the food and the consumer can be observed but there is no sign of the biomagnification phenomenon. The retention rate of the radionuclide is only about 1·5% and the 65Zn concentration in the gammarids remains markedly inferior to that of the ingested food.The elimination of the 65Zn fixed directly from water takes place according to an exponential model which corresponds to the existence of three biological half-lives of the radionuclide, . The excretion of 65Zn accumulated from food is a simple exponential phenomenon which corresponds to only one biological half-life of approximately 17 days. 相似文献